3,683 research outputs found
Optical Properties of (SrMnO3)n/(LaMnO3)2n superlattices: an insulator-to-metal transition observed in the absence of disorder
We measure the optical conductivity of (SrMnO3)n/(LaMnO3)2n superlattices
(SL) for n=1,3,5, and 8 and 10 < T < 400 K. Data show a T-dependent insulator
to metal transition (IMT) for n \leq 3, driven by the softening of a polaronic
mid-infrared band. At n = 5 that softening is incomplete, while at the
largest-period n=8 compound the MIR band is independent of T and the SL remains
insulating. One can thus first observe the IMT in a manganite system in the
absence of the disorder due to chemical doping. Unsuccessful reconstruction of
the SL optical properties from those of the original bulk materials suggests
that (SrMnO3)n/(LaMnO3)2n heterostructures give rise to a novel electronic
state.Comment: Published Online in Nano Letters, November 8, 2010;
http://pubs.acs.org/doi/abs/10.1021/nl1022628; 5 pages, 3 figure
Correlation functions, null polygonal Wilson loops, and local operators
We consider the ratio of the correlation function of n+1 local operators over
the correlator of the first n of these operators in planar N=4 super-Yang-Mills
theory, and consider the limit where the first n operators become pairwise null
separated. By studying the problem in twistor space, we prove that this is
equivalent to the correlator of a n-cusp null polygonal Wilson loop with the
remaining operator in general position, normalized by the expectation value of
the Wilson loop itself, as recently conjectured by Alday, Buchbinder and
Tseytlin. Twistor methods also provide a BCFW-like recursion relation for such
correlators. Finally, we study the natural extension where n operators become
pairwise null separated with k operators in general position. As an example, we
perform an analysis of the resulting correlator for k=2 and discuss some of the
difficulties associated to fixing the correlator completely in the strong
coupling regime.Comment: 34 pages, 6 figures. v2: typos corrected and references added; v3:
published versio
Experimental evidence of antiproton reflection by a solid surface
We report here experimental evidence of the reflection of a large fraction of
a beam of low energy antiprotons by an aluminum wall. This derives from the
analysis of a set of annihilations of antiprotons that come to rest in rarefied
helium gas after hitting the end wall of the apparatus. A Monte Carlo
simulation of the antiproton path in aluminum indicates that the observed
reflection occurs primarily via a multiple Rutherford-style scattering on Al
nuclei, at least in the energy range 1-10 keV where the phenomenon is most
visible in the analyzed data. These results contradict the common belief
according to which the interactions between matter and antimatter are dominated
by the reciprocally destructive phenomenon of annihilation.Comment: 5 pages with 5 figure
Membrane-Based, Liquid–Liquid Separator with Integrated Pressure Control
We describe the development and application of an improved, membrane-based, liquid–liquid separator. Membrane-based separation relies on the exploitation of surface forces and the use of a membrane wetted by one of the phases; however, successful separation requires accurate control of pressures, making the operation and implementation cumbersome. Here we present an improved separator design that integrates a pressure control element to ensure that adequate operating conditions are always maintained. Additionally, the integrated pressure control decouples the separator from downstream unit operations. A detailed examination of the controlling physical equations shows how to design the device to allow operation across a wide range of conditions. Easy to implement, multistage separations such as solvent swaps and countercurrent extractions are demonstrated. The presented design significantly simplifies applications ranging from multistep synthesis to complex multistage separations.Novartis-MIT Center for Continuous ManufacturingUnited States. Defense Advanced Research Projects Agency (Grant N66001-11-C-4147
The Snapshot Hubble U-Band Cluster Survey (SHUCS) II. Star Cluster Population of NGC 2997
We study the star cluster population of NGC 2997, a giant spiral galaxy
located at 9.5 Mpc and targeted by the Snapshot Hubble U-band Cluster Survey
(SHUCS). Combining our U-band imaging from SHUCS with archival BVI imaging from
HST, we select a high confidence sample of clusters in the circumnuclear ring
and disk through a combination of automatic detection procedures and visual
inspection. The cluster luminosity functions in all four filters can be
approximated by power-laws with indices of to . Some deviations
from pure power-law shape are observed, hinting at the presence of a high-mass
truncation in the cluster mass function. However, upon inspection of the
cluster mass function, we find it is consistent with a pure power-law of index
despite a slight bend at M. No
statistically significant truncation is observed. From the cluster age
distributions, we find a low rate of disruption () in both the
disk and circumnuclear ring. Finally, we estimate the cluster formation
efficiency () over the last 100 Myr in each region, finding %
for the disk, % for the circumnuclear ring, and % for the
entire UBVI footprint. This study highlights the need for wide-field UBVI
coverage of galaxies to study cluster populations in detail, though a small
sample of clusters can provide significant insight into the characteristics of
the population.Comment: 31 pages, 9 figures, accepted to the A
Reverse remodeling in Dilated Cardiomyopathy: Insights and future perspectives
Dilated Cardiomyopathy (DCM) has been classically considered a progressive disease of the heart muscle that inexorably progresses towards refractory heart failure, ventricular arrhythmias and heart transplant. However, the prognosis of DCM has significantly improved in the past few years, mostly as the result of successful therapy-induced reverse remodeling. Reverse remodeling is a complex process that involves not only the left ventricle, but also many other cardiac structures and it is now recognized both as a measure of therapeutic effectiveness and as an important prognostic tool. Nevertheless, several aspects of reverse remodeling remain unclear, including the best timing for its quantification, its predictors and its interaction with individual genetic backgrounds. In this review, we summarize our current understanding of reverse remodeling in patients with DCM and provide practical recommendations for the clinical management of this challenging patient population
Evidence for Environmentally Dependent Cluster Disruption in M83
Using multi-wavelength imaging from the Wide Field Camera 3 on the Hubble
Space Telescope we study the stellar cluster populations of two adjacent fields
in the nearby face-on spiral galaxy, M83. The observations cover the galactic
centre and reach out to ~6 kpc, thereby spanning a large range of environmental
conditions, ideal for testing empirical laws of cluster disruption. The
clusters are selected by visual inspection to be centrally concentrated,
symmetric, and resolved on the images. We find that a large fraction of objects
detected by automated algorithms (e.g. SExtractor or Daofind) are not clusters,
but rather are associations. These are likely to disperse into the field on
timescales of tens of Myr due to their lower stellar densities and not due to
gas expulsion (i.e. they were never gravitationally bound). We split the sample
into two discrete fields (inner and outer regions of the galaxy) and search for
evidence of environmentally dependent cluster disruption. Colour-colour
diagrams of the clusters, when compared to simple stellar population models,
already indicate that a much larger fraction of the clusters in the outer field
are older by tens of Myr than in the inner field. This impression is quantified
by estimating each cluster's properties (age, mass, and extinction) and
comparing the age/mass distributions between the two fields. Our results are
inconsistent with "universal" age and mass distributions of clusters, and
instead show that the ambient environment strongly affects the observed
populations.Comment: 6 pages, 3 figures, MNRAS in pres
O2Activation over Ag-Decorated CeO2(111) and TiO2(110) Surfaces: A Theoretical Comparative Investigation
Periodic spin-polarized hybrid density functional theory calculations have been performed to investigate the reactivity of pristine, O-defective, and Ag-decorated CeO2(111) and TiO2(110) surfaces with a small Ag10 cluster toward O2. The adsorption of O2 and its subsequent dissociation have been studied in order to provide a better understanding of the role of the oxide, the metallic nanoparticle, and their interaction in the reactivity of composite metal/metal oxide materials toward O2, as potential catalysts to this reaction. Structural, energetic, electronic, and vibrational properties of all species involved in the different reaction paths considered have been fully characterized. On the stoichiometric surfaces, Ag10 is oxidized and reduces surface Ce4+/Ti4+ ions, while on the O-defective surfaces, the adhesion of silver is promoted only on CeO2 but unfavored on TiO2. On the other hand, on the silver-free supports, O2 strongly adsorbs at vacancies and preferentially reduces to peroxide. When no O vacancies are considered on the Ag10-decorated supports, the net positive charge on Ag10 actually prevents the adsorption and reduction of O2. Instead, when O vacancies are included, two reaction pathways are observed; oxygen molecules can weakly absorb on the silver cluster as a superoxide moiety or strongly adsorb at the vacancy as peroxide. The dissociation of the O-O bond of the peroxide is favored both from the thermodynamic and kinetic points of view in silver-decorated surfaces, in contrast with the silver-free cases. In addition, Ag10/CeO2 shows higher activity toward the O2 adsorption and dissociation than Ag10/TiO2, which can be related both to the higher ionicity and superior electron storage/release ability of ceria with respect to titania, thus leading to the weakening of the O-O bond and providing lower activation barriers for oxygen reduction. These results deepen the current understanding of the reactivity of metal/metal oxide composites toward O2, especially elucidating how the surface stoichiometry affects the charge state of the metal clusters, and hence the reactivity of these interfaces toward O2, with potential important consequences when such composites are considered for catalytic applications
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